By Gerard Caneba
This monograph is a follow-up fabric to the 1st FRRPP publication via Gerard Caneba in 2009. It contains extra conceptual effects, implementation of the FRRPP technique in emulsion media to provide a variety of block copolymers, and different FRRPP-related supplementary issues. Conceptual subject matters contain the appliance of the quantitative research awarded within the first FRRPP monograph for the prevalence of the FRRPP method to the polysterene-styrene-ether (PS-S-Ether) and poly(methacrylic acid)-methacrylic acid-water (PMAA-MAA-Water) structures, in addition to extensions via unsteady country research of the incidence of flat temperature profiles. additionally, the generalization of the quantitative research is completed to contemplate molecular weight results, specifically in keeping with alterations of the section envelope to an hourglass style. subject matters in implementation of the FRRPP procedure from pre-emulsions of monomers and the solvent/precipitant are highlighted. extra FRRPP issues are incorporated during this monograph that pertain to newer efforts of Gerard Caneba, equivalent to oil spill regulate, oil dispersant approach, and caustic sludge remediation from emulsion-based FRRPP fabrics, hydrolysis of vinyl acetate-acrylic acid-based copolymers, and different polymer amendment stories from FRRPP-based emulsions.
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Extra resources for Emulsion-based Free-Radical Retrograde-Precipitation Polymerization
5 Nomenclature 15 will show unsteady-state temperature profiles for the PS–S–Ether and PMAA– MAA–Water systems, and make comparisons with the above-mentioned quasisteady-state-based analysis. Differences in PDI values can also be explained by the closeness of binodal curves at higher molecular weights. This can be seen from the phase diagrams for both the PS–S–Ether and PMAA–MAA–Water systems (Caneba 2010), and from various other types of phase equilibria data of polymer solutions. The case of the PMAA–MAA–Water system illustrates that flatness of temperature profiles within reacting particles does not necessarily result in less broad MWDs, if molecular weights are relatively large.
Dimensionless radial distance, or f) for parameter set 3. 0. 0, 10) involving Parameter Sets 6–10 (Figs. 2 Dimensionless T Fig. 5 Temperature profile evolution (Dimensionless temperature, Y vs. dimensionless radial distance, or f) for parameter set 4. 0. 2 Dimensionless T Fig. 6 Temperature profile evolution (Dimensionless temperature, Y vs. dimensionless radial distance, or f) for parameter set 5. 0. 5 Dimensionless r 2 6 5 Dimensionless T Fig. 7 Temperature profile evolution (Dimensionless temperature, Y vs.
G. Caneba and Y. 1 4 LCST–UCST-Based Copolymerizations Case 1: Monomer 2 Produces Homopolymer at an Operating Temperature Above the LCST This case is typified by the use of S as Monomer 2, and the one-pot copolymerization is done in ether at 80 C. Product properties from the S-AA copolymers made from this methodology are presented in Chaps. 3 and 4 of Caneba (2010). Monomer 1 is AA, wherein it was established that its polymer forms below-UCST behavior at the operating temperature. The progression of the reaction trajectory in the temperature–composition phase diagram plots is shown in Fig.