Encyclopedia of Electrochemistry, Corrosion and Oxide Films - download pdf or read online

By Allen J. Bard, Martin Stratmann, Gerald S. Frankel

Unrivalled in its breadth and intensity, this 11-volume encyclopedia presents either a simple creation to all subject matters regarding glossy electrochemistry in addition to a accomplished review of the topic. all through, the emphasis is in quick access to info, with each subject handled at an introductory, medium and complex point. This top quality reference paintings is edited and written by means of well known scientists, masking every thing from primary learn to components of software. Alan Bard, skilled editor of the magazine of the yank Chemical Society, is likely one of the most famed specialists in electrochemistry and one of many editors-in-chief.

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11 41 1 Fundamentals corrosion rate (from Icorr,M to IM−Pt, A ). This is a result of increased surface area available for the cathodic reaction and the higher exchange current density for hydrogen evolution on Pt relative to M. Consider the case of a sample of M connected to an area of Pt that is 10 times larger. The exchange current (not current density) for the hydrogen evolution reaction on Pt increases by a factor of 10 because of the larger area. This is represented in Fig. 11 by the subscripts A and 10A.

Fontana, N. Greene, Corrosion Engineering, McGraw-Hill, New York, 1978. 3. H. H. Uhlig, Corrosion and Corrosion Control, John Wiley & Sons, New York, 1971. 4. H. , 1985. 5. A. Bard, L. Faulkner, Electrochemical Methods, John Wiley & Sons, New York, 1980. 6. D. A. , 1996. 7. J. O’M. Bockris, A. K. N. Reddy, Modern Electrochemistry, Plenum Press, New York, 1970. 8. L. L. Shreir, R. A. Jarman, G. T. ), Corrosion, Butterworth-Heinemann, Oxford, 1994. 9. , ASM International, Metals Park, Ohio, 1987, 1–1415, Vol.

The corrosion current is given by the intersection of the two potential-current polarization curves, and the current densities are determined by dividing the current by the electrode areas. 14 Ohmic Potential Drops The passage of current through an ionic electrolyte of finite resistivity results in an ohmic potential drop along the current path according to Ohm’s law. There are two aspects of corrosion that are influenced by ohmic potential drops: measured polarization curves and any form of corrosion in which the anodic and cathodic reactions are separated spatially, such as in galvanic corrosion.

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