By Allen J. Bard, Martin Stratmann, Israel Rubinstein, Masamichi Fujihira, James F. Rusling
This 11-volume encyclopedia offers either a simple creation to all issues relating to glossy electrochemistry in addition to a finished evaluation of the topic. Unrivalled in its breadth and intensity, this average reference has been created and written through popular scientists, protecting every thing from primary study to parts of program.
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Additional info for Encyclopedia of Electrochemistry, Modified Electrodes
We can adopt their structures into the backbone units of component molecules of SAMs, just like alkane chains in alkanethiol-based SAMs. This strategy was already described in Sect. 6 using BCO-based SAMs . Fujihira and coworkers also demonstrated that a stable adamantanebased SAM was formed successfully on a gold (111) surface . Recently, Weiss and coworkers have also examined the property of a SAM using an adamantanethiol derivative . The structural difference between the two adamantanebased components of the SAMs is the presence or the absence of a methylene spacer connecting between a rigid adamantane unit and a thiol head group.
Michel and coworkers reported a high-resolution printing technique based on transferring a pattern from an elastomeric stamp to a solid substrate by conformal contact, and described the potential for emerging micro- and nanoscale patterning technologies [91, 341]. Several new approaches using µCP have been reported. Patterned SAMs on gold can be prepared by the combination of µCP and the subsequent solution deposition methods . µCP can be applied to the top surface of a SAM, which leads to a new type of lithographic approach to prepare patterned SAMs using a locally selective catalytic reaction [341, 343].
Fig. 2 Close-packed Structure of SAMs Full-coverage on Gold (111) Surface structure of long-chain alkanethiol-based SAMs, such as octanethiol (C8)-SAM, decanethiol (C10)-SAM, and longer is on the effect of intermediate backbone spacer on the SAM structure. Here, these structural aspects of importance for characteristics of SAMs prepared on gold (111) will be summarized. 2 Å S S Au(111) S (b) Side view Schematics depicting from two different perspectives for the structural models of the arrangement of a close-packed adlattice structure of decanethiol-based SAM on a gold (111) surface.